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Tips for SYSTEM, Liquid Coolants MATERIAL SAFETY DATA SHEET RADIATOR COOLANT   and how it is implemented | Valeo Service

Technical Service Bulletin for SYSTEM, Liquid Coolants, 559100 - Valeo Service

MATERIAL SAFETY DATA SHEET RADIATOR COOLANT

<h3>SECTION 1. PRODUCT AND COMPANY IDENTIFICATION</h3>

Product Name

Marketer or supplier's&nbsp;

Emergency telephone number

Recommended use

&nbsp;

Email contact

Coolant

Valeo India Private Limited

044-71027508

Radiator Coolant. For specific application advice see appropriate Technical Data Sheet or consult our company representative.

alert.india@valeo.com

<table border="1" cellpadding="1" cellspacing="1" style="width: 773.6px;">
	<tbody>
		<tr>
			<td style="width: 158px;">GHS Classification</td>
			<td style="width: 604px;">ACUTE TOXICITY (oral) - Category 5 REPRODUCTIVE TOXICITY (Unborn child) - 2 SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2</td>
		</tr>
	</tbody>
</table>

GHS label elements

<table border="1" cellpadding="1" cellspacing="1" style="width: 685.6px;">
	<tbody>
		<tr>
			<td style="width: 159px;">Signal word</td>
			<td style="width: 515px;">Warning</td>
		</tr>
		<tr>
			<td style="width: 159px;">Hazard statements</td>
			<td style="width: 515px;">&nbsp;</td>
		</tr>
		<tr>
			<td style="width: 159px;">H303</td>
			<td style="width: 515px;">May be harmful if swallowed.</td>
		</tr>
		<tr>
			<td style="width: 159px;">H361</td>
			<td style="width: 515px;">Suspected of damaging the unborn child.</td>
		</tr>
		<tr>
			<td style="width: 159px;">H373</td>
			<td style="width: 515px;">May cause damage to organs through prolonged or repeated exposure</td>
		</tr>
	</tbody>
</table>

Precautionary statements

Prevention

<table border="1" cellpadding="1" cellspacing="1" style="width: 705.6px;">
	<tbody>
		<tr>
			<td style="width: 155px;">P201</td>
			<td style="width: 539px;">Obtain special instructions before use.</td>
		</tr>
		<tr>
			<td style="width: 155px;">P202</td>
			<td style="width: 539px;">Do not handle until all safety precautions have been read and understood</td>
		</tr>
		<tr>
			<td style="width: 155px;">P280</td>
			<td style="width: 539px;">Wear protective gloves. Wear eye or face protection. Wear protective clothing.</td>
		</tr>
		<tr>
			<td style="width: 155px;">P260</td>
			<td style="width: 539px;">Do not breathe vapour</td>
		</tr>
	</tbody>
</table>

Response

<table border="1" cellpadding="1" cellspacing="1" style="width: 710.6px;">
	<tbody>
		<tr>
			<td style="width: 155px;">P314</td>
			<td style="width: 544px;">Get medical attention if you feel unwell.</td>
		</tr>
		<tr>
			<td style="width: 155px;">P308 + P313</td>
			<td style="width: 544px;">IF exposed or concerned: Get medical attention.</td>
		</tr>
		<tr>
			<td style="width: 155px;">P301 + P312</td>
			<td style="width: 544px;">IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell.</td>
		</tr>
	</tbody>
</table>

Storage

<table border="1" cellpadding="1" cellspacing="1" style="width: 715.6px;">
	<tbody>
		<tr>
			<td style="width: 150px;">P405</td>
			<td style="width: 554px;">Store locked up</td>
		</tr>
	</tbody>
</table>

Disposal

<table border="1" cellpadding="1" cellspacing="1" style="width: 719.6px;">
	<tbody>
		<tr>
			<td style="width: 151px;">P501</td>
			<td style="width: 557px;">Dispose of contents and container in accordance with all local, regional, national and international regulations.</td>
		</tr>
	</tbody>
</table>

&nbsp;

SECTION 2. HAZARDS IDENTIFICATION

<h3>Section 3. Composition/information on ingredients</h3>

Substance / Mixture

Chemical nature

Mixture.

Mixture of ethylene glycol, and additives

<table border="1" cellpadding="1" cellspacing="1" style="width: 500px;">
	<tbody>
		<tr>
			<td>Ingredient name</td>
			<td>%</td>
			<td>CAS number</td>
		</tr>
		<tr>
			<td>Ethylene glycol</td>
			<td>≥10 - ≤25</td>
			<td>107-21-1</td>
		</tr>
	</tbody>
</table>

&nbsp;

<h3>Section 4. First aid measures</h3>

Eye contact

&nbsp;

Inhalation

&nbsp;

Skin contacts

&nbsp;

Ingestion

&nbsp;

&nbsp;

Protection of first aiders

Description of necessary first aid measures 

Immediately flush eyes with large amounts plenty of water for 15 minutes. Get medical attention if irritation persists.

If inhaled, remove to fresh air. Get medical attention.

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention.

Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. If necessary, call a poison center or physician. Get medical attention.

No action should be taken that involves personal risk or is performed without appropriate training. Providing mouth-to-mouth resuscitation may pose a danger to the person giving aid.

&nbsp;

Indication of immediate medical attention and special treatment needed, if necessary

Specific treatments Indication of immediate Ethylene Glycol: Gastric irrigation, ethanol or fomepizole may have value in treatment. Consult physician

<h3>Section 5. Firefighting measures</h3>

Extinguishing media

Suitable&nbsp; &nbsp; &nbsp; &nbsp; &nbsp;In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray.

Not suitable&nbsp; Do not use water jet

Specific hazards arising from the chemical A solid stream of water or foam directed into hot, burning liquid can cause frothing. Burning may produce carbon monoxide and carbon dioxide.

Special precautions for firefighter&nbsp;&nbsp;No action shall be taken involving any personal risk or without suitable training. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.

Special protective equipment for fire-fighters&nbsp;&nbsp;Proper protective equipment including chemical resistant gloves is to be worn; chemical resistant suit is indicated if large contact with spilled product is expected. Self-Contained Breathing Apparatus must be worn when approaching a fire in a confined space. Select fire fighter's clothing approved to relevant Standards

Personal precautions, protective equipment and emergency procedures: Avoid contact with skin and eyes.

Environmental precautions Local authorities should be advised if significant spillages cannot be contained

Methods and material for containment and cleaning up

Small spill&nbsp; Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor

Large spill&nbsp; Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Contaminated absorbent material may pose the same hazard as the spilt product. Dispose of via a licensed waste disposal contractor

Section 6. Accidental release measures

Precautions for safe handling

Protective measures&nbsp;&nbsp; &nbsp;Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Advice on general&nbsp; &nbsp; Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures

Conditions for safe storage Store&nbsp;&nbsp; &nbsp;in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/ containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers.

Not suitable&nbsp; &nbsp;Prolonged exposure to elevated tempe

&nbsp;

Section 7. Handling and storage 

Control parameters 

Occupational exposure limits

<table border="1" cellpadding="1" cellspacing="1" style="width: 754.6px;">
	<tbody>
		<tr>
			<td style="width: 120px;">Ingredient name</td>
			<td style="width: 623px;">Exposure limits</td>
		</tr>
		<tr>
			<td style="width: 120px;">Ethylene glycol</td>
			<td style="width: 623px;">ACGIH TLV (United States, 3/2017). STEL: 10 mg/m³ 15 minutes. Form: Inhalable fraction. Aerosol only. STEL: 50 ppm 15 minutes. Form: Vapor fraction TWA: 25 ppm 8 hours. Form: Vapor fraction</td>
		</tr>
	</tbody>
</table>

Recommended monitoring procedures&nbsp; &nbsp; &nbsp;If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the eƯectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Appropriate engineering controls&nbsp; &nbsp; Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits. All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained. Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards. The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible

Environmental exposure controls&nbsp; &nbsp; Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures&nbsp; &nbsp;&nbsp; Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Eye protection Safety glasses with side shields.

Hand protection&nbsp; &nbsp;Wear suitable gloves. The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application.

Skin protection&nbsp; &nbsp;Use of protective clothing is good industrial practice. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Other skin protection&nbsp; &nbsp; Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection&nbsp; &nbsp;In case of insuƯicient ventilation, wear suitable respiratory equipment. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment.

Section 8. Exposure controls/personal protection 

 Appearance&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; Liquid

 Colour&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; Green/Red/Blue

 Odour&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp;Characteristic

 pH&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp;7 to 11

 Flash point&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp;&gt;120 °C

 Density at 20 °C Min.&nbsp; &nbsp; &nbsp; &nbsp; 1.03 kg/m3

Section 9. Physical and chemical properties 

Reactivity&nbsp; &nbsp; &nbsp;No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.

Chemical stability&nbsp;&nbsp; the product is stable

Possibility of hazardous&nbsp; &nbsp;&nbsp;Under normal conditions of storage and use, hazardous reactions will not occur

Reactions&nbsp; &nbsp; Under normal conditions of storage and use, hazardous polymerisation will not occur.

Conditions to avoid Avoid excessive heat Incompatible materials&nbsp; &nbsp;Reactive or incompatible with the following materials: oxidising materials

Hazardous decomposition&nbsp;products&nbsp; &nbsp;Under normal conditions of storage and use, hazardous decomposition products should not be produced.

 Section 10. Stability and reactivity 

Health Hazard summary&nbsp; No adverse health effects are anticipated with normal use of this product.

Eye&nbsp; Exposure may result in irritation and lacrimation.

Inhalation&nbsp; Adverse health effects are not anticipated under normal conditions of use.

Skin&nbsp;&nbsp;Prolonged and repeated contact with the skin may result in mild Irritation

Ingestion&nbsp;Ingestion may result in headache, nausea, vomiting, gastrointestinal irritation and diarrhoea. &nbsp;

Toxicity&nbsp;&nbsp;LD50 data not available.

11. TOXICOLOGICAL INFORMATION

Environmental Effects This product is not anticipated to cause adverse eƯects to animal or plant life if released to the environment In small quantities. Not expected to bio accumulate.

Eco toxicity No data available. Persistence &amp; Degradability This product is readily biodegradable.

Mobility Miscible in water, and likely to be transported considerable distances in soil.

12. ECOLOGICAL INFORMATION

Waste Disposal&nbsp; &nbsp; Check governmental regulations and local authorities for approved disposal of this material

Legalization&nbsp;&nbsp;The recovered liquid may be utilized or disposed of as per local pollution board’s recommendations.

13. DISPOSAL CONSIDERATIONS 

ADR/RID Not applicable

International Shipping Information IMO

Shipping Name&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; Not applicable/Not Regulated

Hazard Class&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp;Not applicable

Subsidiary Class&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; Not applicable

UN Number&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; Not applicable

Packing Group&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp;Not applicable

Transport Label&nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; &nbsp; Not Required&nbsp;

14. TRANSPORT INFORMATION

SDS prepared according to Regulation.

Advice related to training

Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and interpretation of this safety data sheet, as well as the label on the product.

15. REGULATORY INFORMATION 

Disclaimer:

VALEO INDIA PVT. LTD. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

16. OTHER INFORMATION 